Our group focuses on the ‘Directing Group’ free C-H functionalization through ‘Carbene Transfer’ reactions using novel transition metal or organometallic complexes as catalysts. The relatively inert nature of the strong C-H bond demands the syntheses of specially designed sophisticated catalysts for this method to be employed as the sustainable route for a diverse array of synthetic transformations. One of the major challenges of C-H functionalization is to attain the regioselectivity as there are multiple C-H bonds present in the same molecule.
Read moreComplexes containing transition metal atoms in different oxidation states are involved in many fundamental processes. They often act as catalysts in various organic transformations. Mechanistic investigations lead to the general conclusion that complexes with higher coordinate metals undergo ligand-dissociation in solution to produce reactive intermediates containing low coordinate metals having available substrate binding sites.
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