List of Scientific Publications

7. Sudipta Roy, Kartik Chandra Mondal, Jann Meyer, Benedikt Niepötter, Christian Köhler, Regine Herbst-Irmer, Dietmar Stalke, Birger Dittrich, Diego M. Andrada, Gernot Frenking, Herbert W. Roesky. Syntheses, Characterization and Theoretical Investigation of Two Coordinate Palladium(0) and Platinum(0) Complexes Utilizing π-accepting Carbenes.


Abstract: π-Accepting cyclic alkyl(amino) carbenes were employed for the preparation of two coordinate and bent palladium(0) and platinum(0) complexes. The palladium complex exhibits crystallochromism (from maroon to green) due to controlled bending of C-Pd-C bond angle by ~6° during the elimination of a lattice solvent molecule. The bonding and stability of these complexes are studied by theoretical calculation.

Inside Cover: Syntheses, Characterization and Theoretical Investigation of Two Coordinate Palladium(0) and Platinum(0) Complexes Utilizing π-accepting Carbenes.


Sudipta Roy, Kartik Chandra Mondal, Jann Meyer, Benedikt Niepötter, Christian Köhler, Regine Herbst-Irmer, Dietmar Stalke, Birger Dittrich, Diego M. Andrada, Gernot Frenking, Herbert W. Roesky.